Designing an electrocatalyst that simultaneously satisfies high catalytic activity and surface stability is essential for realizing high-performance lithium-sulfur (Li||S) batteries. Here, we propose an advanced electrocatalyst by constructing a thin protective catalytic layer (PCL) on the surface of metal nanoparticle catalysts. This few atomic layer thicknesses of the PCL composed of pyridinic N embedded graphitic carbon allows electrons to transfer from a metal nanoparticle to pyridinic N, resulting in an optimized p-orbital level of pyridinic N of PCL favorable for highly active conversion reaction of lithium sulfide. Further, PCL suppresses the direct contact of sulfur species with metal electrocatalysts. This surface protection effect inhibits the phase change of metal electrocatalysts to metal sulfide impurities, which maintains a highly active Li||S electrocatalysis for long-term cycling. Consequently, A h-level Li||S pouch cell with >
500 W h kg