Light-based three-dimensional (3D) printing technologies are regarded as one of the most promising manufacturing methods. However, 3D printed objects based on free radical polymerization have disadvantages such as anisotropy, poor mechanical strength, and heat resistance and cannot meet the requirements of high-performance applications. This study reports a class of acryloyl-functional benzoxazine exhibiting excellent mechanical properties, heat resistance, and flame retardancy. 3-Acryloyl-3,4-dihydro-2