Molecular insights and rational engineering of a compact CRISPR-Cas effector Cas12h1 with a broad-spectrum PAM.

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Tác giả: Chunyi Hu, Shiqing Huang, Hongyu Li, Zekai Li, Bo Liu, Mengxi Liu, Songying Ouyang, Yuhang Wei, Chenyang Xiong, Weiwei Zheng

Ngôn ngữ: eng

Ký hiệu phân loại: 512.782 Rational numbers

Thông tin xuất bản: England : Signal transduction and targeted therapy , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 142702

 Cas12h1 is a compact CRISPR-associated nuclease from functionally diverse type V CRISPR-Cas effectors and recognizes a purine-rich protospacer adjacent motif (PAM) distinct from that of other type V Cas effectors. Here, we report the nickase preference of Cas12h1, which predominantly cleaves the nontarget strand (NTS) of a double-stranded DNA (dsDNA) substrate. In addition, Cas12h1 acts as a nickase in human cells. We further determined the cryo-EM structures of Cas12h1 in the surveillance, R-loop formation, and interference states, revealing the molecular mechanisms involved in the crRNA maturation, target recognition, R-loop formation, nuclease activation and target degradation. Cas12h1 notably recognizes a broad 5'-DHR-3' PAM (D is A, G, or T
  H is A, C, or T
  R is A or G) both in vitro and in human cells. In addition, Cas12h1 utilizes a distinct activation mechanism that the lid motif undergoes a "flexible to stable" transition to expose the catalytic site to the substrate. A high-fidelity nucleic acid detector, Cas12h1
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