Structure-Induced Reversing Basicity of α-Anionic Fischer Carbenes.

• Tác giả: Yu-Hua Guo, Zhen Wang, Ming-Tian Zhang
• Ngôn ngữ: eng
• Ký hiệu phân loại: 594.38 *Pulmonata
• Thông tin xuất bản: United States : Inorganic chemistry , 2025
• Bộ sưu tập: NCBI
• ID: 161699

Tóm tắt

Group VI metal carbenes and their α-anionic complexes play an important role in organic synthesis, yet structural characterizations and thermodynamic studies for reactive α-anions remain challenging. This work investigated the molecular structures and thermodynamics of α-anionic Fischer carbenes and their conjugated acids. The results clarify the negative charge localized on the M(CO)