This study investigates the potential of superheated steam (SS) as a rapid and sustainable method for synthesising millet starch citrates with improved physicochemical and functional properties. Millet starch was esterified with citric acid (CA) under varying SS conditions (160-180 °C, 15-45 min) to optimise the degree of substitution (DS) and evaluate its influence on starch functionality. A range of DS values (0.023 to 0.121) were achieved, with the highest DS observed at 170 °C for 45 min. Structural analysis using Fourier-transform infrared spectroscopy confirmed successful esterification, with the appearance of a new peak at 1735 cm