Fluorination from Surface to Bulk Stabilizing High Nickel Cathode Materials with Outstanding Electrochemical Performance.

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Tác giả: Guihong Mao, Laifa Shen, Jieyu Yang, Tengyu Yao, Yan Yu

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: Germany : Angewandte Chemie (International ed. in English) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 176005

High nickel layered oxides provide high energy densities as cathodes for next-generation batteries. However, critical issues such as capacity fading and voltage decay, which derive from labile surface reactivity and phase transition, especially under high-rate high-voltage conditions, prevent their commercialization. Here we propose a fluorination strategy to simultaneously introduce F atoms into oxygen layer and create a F aggregated interface. Substitution F for O stabilizes the layered ionic framework as the F ions can anchor the internal transition metal ions through strong TM-F bonding interaction, alleviating anisotropic lattice strain accumulation and release during the cycle, and promoting the Li
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