Ligand-Shell Cooperativity in a Bilayer Silica-Sandwiched Mixed-Metals Nanocatalyst Design for Absolute Selectivity Switch.

• Tác giả: Anubhab Acharya, Hee Cheul Choi, Byeong Su Gu, Sampathkumar Jeevanandham, Hyun Woo Kim, Amit Kumar, Nitee Kumari, Dongmin Lee, In Su Lee, Ankur Maji, Youngkwan Yoon, Yongju Yun
• Ngôn ngữ: eng
• Ký hiệu phân loại: 553.499 Metals not provided for elsewhere
• Thông tin xuất bản: United States : ACS nano , 2025
• Bộ sưu tập: NCBI
• ID: 177518

Tóm tắt

Unlike homogeneous metal complexes, achieving absolute control over reaction selectivity in heterogeneous catalysts remains a formidable challenge due to the unguided molecular adsorption/desorption on metal-surface sites. Conventional organic surface modifiers or ligands and rigid inorganic and metal-organic porous shells are not fully effective. Here, we introduce the concept of "ligand-porous shell cooperativity" to desirably