Solvent-controlled silver catalyzed radical transformation of α-imino-oxy acids with cyclic aldimines.

• Tác giả: Sheng Cao, Ke Cui, Mingyue Cui, Feng Li, Xueqi Li, Yuran Qin, Qin Shen, Jingjing Wang, Teng Wang, Linbo Zhang
• Ngôn ngữ: eng
• Thông tin xuất bản: England : Chemical communications (Cambridge, England) , 2025
• Bộ sưu tập: NCBI
• ID: 177607

Tóm tắt

A silver-catalyzed cross coupling of cyclic aldimines and α-imino-oxy acids has been developed. The solvent-dependent reaction could selectively deliver either cyclic imine moiety retained nitriles or ring-opened oxonitriles in moderate yields. The mechanistic studies show that the reaction undergoes a radical pathway.