As a promising post lithium-ion-battery candidate, manganese metal battery (MMB) is receiving growing research interests because of its high volumetric capacity, low cost, high safety and high energy-to-price ratio. However, the low energy density, mainly constrained by scarce choices and unsatisfying capacity of cathodes, strictly bottlenecks the development of MMBs. In this work, a new class of cathodes based on novel dual-storage mechanism (DSM) are reported. Working principles of DSM are revealed and deeply understood via ex situ X-ray diffraction and X-ray photoelectron spectroscopy. Besides, a proof-of-concept DSM-based Cu