Technological advances have led to a proportional increase in the deposition of contaminants across various environmental compartments, including water sources. Heavy metals, also known as potentially toxic metals, are of particular concern due to their significant harmful impacts on environmental and human health. Among the available methods for mitigating the threat of these metals in water, solar radiation-based technologies stand out for their cleanliness, cost-effectiveness, and efficiency in removing or reducing the toxicity of heavy metals. The performance and productivity of these methods in removing heavy metals such as arsenic (As), chromium (Cr), mercury (Hg), and uranium (U) from water still need to be comprehensively synthesized. Thus, this work aims to address that gap. The performance, potential, and challenges of real-world applications of conventional solar stills (CSS), membrane-based solar stills, and solar heterogeneous photocatalysis are concisely summarized and critically reviewed. CSS and membrane-based stills are highly effective (efficacy >
98%) in removing and capturing heavy metals from water. However, structural and functional improvements are needed to enhance productivity (especially for CSS) and usability in real-world environmental remediation and drinking water supply scenarios. Solar heterogeneous photocatalysis is highly effective in removing and/or converting As, Cr, Hg, and U into their non-toxic or less toxic forms, which subsequent processes can easily remove. Further research is necessary to evaluate the safety of photocatalytic materials, their integration into scalable solar reactors, and their usability in real-world environmental remediation applications.