Enzyme-Inspired Single Selenium Site for Selective Oxygen Reduction.

• Tác giả: Zhi-Yao Duan, Gang Fu, Huan Huang, Shi-Gang Sun, Tao Wang, Yu-Cheng Wang, Xia Xu, Wen-Song Yu, Peng-Yang Zhang, Zhi-You Zhou
• Ngôn ngữ: eng
• Ký hiệu phân loại: 006.35 *Natural language processing
• Thông tin xuất bản: Germany : Angewandte Chemie (International ed. in English) , 2025
• Bộ sưu tập: NCBI
• ID: 179068

Tóm tắt

Learning from nature has garnered significant attention in the scientific community for its potential to inspire creative solutions in material or catalyst design. The study highlights the design of a biomimetic single selenium (Se) site-modified carbon (C) moiety that retains the unique reactivity of selenoenzyme with peroxides, which plays crucial roles in selectively catalyzing the oxygen reduction reaction (ORR). The as-designed Se-C demonstrates nearly 100 % 4-electron selectivity, evidenced by 0.039 % of H