Responsive Photonic Filaments from Confined Self-Assembly of Cellulose Nanocrystals.

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Tác giả: Qiongya Li, Guangyan Qing, Zhixiang Wang, Jiaqi Yu, Fusheng Zhang, Wei Zhong

Ngôn ngữ: eng

Ký hiệu phân loại: 271.6 *Passionists and Redemptorists

Thông tin xuất bản: United States : ACS nano , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 179090

Cellulose nanocrystals (CNCs) hold transformative potential for sustainable photonics, particularly in applications such as polarization-selective devices and chiroptical sensors. However, conventional CNC derivatives are primarily limited to dense flat films, restricting their functionalization in soft fibers and wearable textiles. Advancing CNCs into infinitely extending cylindrical filaments presents an opportunity to unlock fascinating applications, yet this transformation is often hindered by the Plateau-Rayleigh instability, leading to the breakup of CNC suspensions into droplets. Here, we propose an innovation strategy for the continuous and scalable production of chiral photonic filaments by confining the photo-cross-linking of CNC/poly(ethylene glycol) diacrylate precursors within cylindrical microtubules. The resulting filaments, driven by both shear flow and chiral self-assembly, exhibit a high degree of orientation along their central axis while preserving the nanohierarchical structure of the uniaxial nematic phase. Notably, these filaments achieve an orientation order parameter of 0.91, coupled with exceptional mechanical performances (14 MJ·m
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