Thermodynamics-inspired identification of privileged organocatalysts for hydrogen evolution reactions.

• Tác giả: Jin-Pei Cheng, Likun Dong, Jin-Dong Yang, Yu-Shan Zhang, Bing Zhong
• Ngôn ngữ: eng
• Ký hiệu phân loại: 297.1248 Sources of Islam
• Thông tin xuất bản: England : Chemical communications (Cambridge, England) , 2025
• Bộ sưu tập: NCBI
• ID: 180377

Tóm tắt

The 7π-aromaticity observed in N-heterocyclic phosphinyl radicals (NHP˙) can offset the energy penalty associated with the disruption of 6π-aromaticity in NHP cations. This property endows NHP hydrides with facile regeneration, rendering NHP privileged organocatalysts for electrochemical hydrogen evolution reactions.