A Facile Strategy to Construct Stretchable and Thermoreversible Double Network Hydrogels with Low Hysteresis and High Toughness Based on Entanglement and Hydrogen Bond Networks.

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Tác giả: Dianhao Gong, Qixiu Jiang, Kun Lei, Xinling Wang

Ngôn ngữ: eng

Ký hiệu phân loại: 025.43 *General classification systems

Thông tin xuất bản: Germany : Macromolecular rapid communications , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 180547

High toughness and low hysteresis are of great significance for stretchable hydrogels to strengthen their reliability and practicability for cycle-loaded applications. Whereas, it is still challenging to simultaneously gain mutually repulsive properties due to the existence of dissipation structure. Here, stretchable and recoverable double network (DN) hydrogels comprising highly entangled network structure and temperature-induced dense hydrogen bond (HB)-associated network structure are synthesized, in which slidable entanglements and dense HBs act as the effective crosslinking in first and second networks, respectively. Moveable entanglements and stable HB structures endow hydrogels with high stretchability (999%), high tensile strength (0.82 MPa) and high fracture toughness (4.51 MJ·m
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