To study the response characteristics of long-term mulching measures on soil enzyme activity and the limitation of microbial nutrients in the Loess Plateau Region, the study adopted a random block design and setup based on the long-term field positioning experiment conducted in 2008. Four types of inter-field management measures were established, including conventional no-mulch (NM), straw mulch (SM), mulch mulch (PM), and ridge mulch (RPM). The changes in soil nutrients and extracellular enzyme activities, their ecological stoichiometry and influencing factors under different cover measures, were investigated using a one-way analysis of variance, a stoichiometric model of soil extracellular enzymes, and redundancy analysis (RDA). The results showed that mulching significantly affected soil basal nutrients (