Synthesis of Selenized Metal-Organic Framework Hollow Cage under Ambient Condition for Clean Energy Applications.

• Tác giả: Hongmei Chen, Lijian Leng, Hailong Li, Minyu Li, Wenqi Qu, Fuyin Xie, Jianping Yang, Zequn Yang, Wei Zheng
• Ngôn ngữ: eng
• Ký hiệu phân loại: 678.72 Synthetic rubber and derivatives
• Thông tin xuất bản: United States : ACS applied materials & interfaces , 2025
• Bộ sưu tập: NCBI
• ID: 184781

Tóm tắt

The synthesis of structured metal organic framework (MOF)-derived selenide composites is a vibrantly emerging research area serving clean energy purposes. However, there is no way to convert MOFs into structured selenide composites under ambient conditions for unknown reasons. This work gave mechanistic insights into how the redox properties and release rate of selenium precursors influenced the structural inheritance behavior of MOFs during the selenization process, explaining why maintaining the morphology of MOFs during a room-temperature aqueous selenization process is a tricky task. A novel method of selenizing structured ZIF-67 into CoSe