Preconcentration-enhanced electrochemical detection of paraoxon in food and environmental samples using reduced graphene oxide-modified disposable sensors.

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Tác giả: Craig E Banks, Márcio F Bergamini, Luís M C Ferreira, Cristiane Kalinke, Luiz H Marcolino-Júnior, Elisa S Orth, Maurício A P Papi, Rafael L Zamboni

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: England : Analytical methods : advancing methods and applications , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 185760

Organophosphates, such as paraoxon, are widely used as insecticides in agriculture, making their detection in environmental and food samples crucial due to their high toxicity. This study presents the development of an electrochemical sensor for the detection of paraoxon, using a screen-printed carbon electrode (SPCE) modified with electrochemically reduced graphene oxide (rGO). The modification enhanced the sensor's electrical conductivity and electrochemical performance. A novel preconcentration approach, involving potential pulses at -1.0 and 0.0 V, was employed to improve the adsorption of paraoxon on the electrode surface. Detection was performed by square wave voltammetry, and under optimized conditions, the rGO-SPCE sensor exhibited a linear range from 1.0 to 30 μmol L
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