Palladium-catalyzed substrate-switchable C-H alkenylation and alkylation of benzoic acids using MBH alcohols.

• Tác giả: Hemanga Bhattacharyya, Tharmalingam Punniyamurthy, Sharajit Saha, Kshitiz Verma
• Ngôn ngữ: eng
• Ký hiệu phân loại: 546.636 *Palladium
• Thông tin xuất bản: England : Chemical communications (Cambridge, England) , 2025
• Bộ sưu tập: NCBI
• ID: 186634

Tóm tắt

Pd-catalyzed carboxylate-directed C-H alkenylation and alkylation of benzoic acids has been achieved by switching the MBH alcohol used as the coupling partner. The alkenylation results in the formation of aryl acrylaldehydes, whereas the alkylation furnishes the formation of α-benzyl β-ketoesters.