Electrochromism stands out as a highly promising technology for applications including variable optical attenuators, optical switches, transparent displays, and dynamic windows. The pursuit of high-contrast tunability in electrochromic devices remains a challenging goal. Here, the first photochromic hydrogel electrolyte is reported for electro- and photo-dual responsive chromatic devices that yield a high transmittance contrast at 633 nm (ΔT = 83.1%), along with a tinted transmittance below 1.5%. Such high-contrast devices not only hold great promise for dynamic windows but also enable seamless transitions between transparent augmented reality (AR) glass and opaque virtual reality (VR) glass. These findings introduce an innovative strategy for the design of high-contrast dimmers, opening new avenues for the development of chromatic devices.