Two Plus Four Equals Three-Iron(II)/Iron(IV) Comproportionation as an Additional Pathway for Iron(IV)-Oxido Reactions.

• Tác giả: Peter Comba, Lena J Daumann, Serhiy Demeshko, Katherine Fisher, Jonathan Gutenthaler-Tietze, Ivana Ivanović-Burmazović, Thomas Josephy, Jan C Kruse, Niko S W Lindlar Né Jonasson, Peter Mayer, Annika Menke, Franc Meyer, David Schmidl, Laura Senft, Andrea Squarcina
• Ngôn ngữ: eng
• Ký hiệu phân loại: 363.232 Patrol and surveillance
• Thông tin xuất bản: United States : Inorganic chemistry , 2025
• Bộ sưu tập: NCBI
• ID: 199069

Tóm tắt

Iron enzymes are ubiquitous in nature. In particular, enzymes with iron-oxygen cofactors as active sites perform a vast variety of reactions. Both iron(III)-hydroxido and iron(IV)-oxido species have been observed to play a catalytically active role. In order to complement biochemical investigations, a large variety of synthetic compounds using these motifs were synthesized in past decades to study and understand their inherent reactivity. One such synthetic model complex is [Fe