Force-Matching-Based Approach for the Generation of Polarizable and Nonpolarizable Force Fields Applied to CsPbI

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Tác giả: Martin P Bircher, Ariadni Boziki, Mathias Dankl, Ursula Rothlisberger, Cecilia Vona

Ngôn ngữ: eng

Ký hiệu phân loại: 327.117 Use of force and threats of force

Thông tin xuất bản: United States : The journal of physical chemistry. C, Nanomaterials and interfaces , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 212901

Lead halide perovskites have emerged as highly efficient solar cell materials. However, to date, the most promising members of this class are polymorphs in which a wide-band-gap δ phase competes with the photoactive perovskite α form and the intrinsic physical interactions that stabilize one phase over the other are currently not well understood. Classical molecular dynamics simulations based on suitably parametrized force fields (FF) enable computational studies over broad temperature (and pressure) ranges and can help to identify the underlying factors that govern relative phase stability at the atomic level. In this article, we present a force-matching-based approach for the automatized generation of polarizable (
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