Paired Electrosynthesis at Interdigitated Microband Array Electrodes without Intentionally Added Electrolyte: C-C Coupling of Dicyanobenzenes with Methanol.

• Tác giả: Tingran Liu, Frank Marken, Claire McMullin, James E Taylor
• Ngôn ngữ: eng
• Ký hiệu phân loại: 541.3724 Miscellaneous topics in physical chemistry
• Thông tin xuất bản: United States : The journal of physical chemistry. C, Nanomaterials and interfaces , 2025
• Bộ sưu tập: NCBI
• ID: 212932

Tóm tắt

The formation of substituted benzyl alcohols from dicyanobenzenes and methanol (C-C coupling) is demonstrated as a model system for paired electrosynthesis and investigated at interdigitated microband array electrodes in a microreactor with/without intentionally added supporting electrolyte. A Pt-Pt microband array with 5 μm bands separated by 5 μm gaps is employed in a dimethyl sulfoxide (DMSO) solvent. Yields are optimized to approximately 50% at the point of 100% conversion. The mechanism is investigated by employing isotope labeling (CD