Promoting C-F Bond Activation for Perfluorinated Compounds Decomposition via Atomically Synergistic Lewis and Brønsted Acid Sites.

• Tác giả: Liyuan Chai, Ting-Shan Chan, Michelle L Coote, Junwei Fu, Cheng-Wei Kao, Zhang Lin, Kang Liu, Min Liu, Tao Luo, Wenjie Luo, Chao Ma, Hang Zhang
• Ngôn ngữ: eng
• Thông tin xuất bản: United States : Journal of the American Chemical Society , 2025
• Bộ sưu tập: NCBI
• ID: 214087

Tóm tắt

Catalytic hydrolysis is a sustainable method for the degradation of perfluorinated compounds (PFCs) but is challenged by the high reaction temperatures required to cleave strong C-F bonds. Herein, we developed an innovative C-F activation strategy by constructing synergistic Lewis and Brønsted acid pairs over atomically dispersed Zn-O-Al sites to promote C-F bond activation for decomposition of typical PFCs, CF