Topological defects in semiconducting carbon nanotubes as triplet exciton traps and single-photon emitters.

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Tác giả: Timur Biktagirov, Uwe Gerstmann, Wolf Gero Schmidt

Ngôn ngữ: eng

Ký hiệu phân loại: 220.4047 Original texts, early versions, early translations

Thông tin xuất bản: England : Nanoscale , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 214213

We investigate how topological defects influence the excitonic behavior in (6,5) semiconducting single-walled carbon nanotubes. Our theoretical study demonstrates that topological defects, particularly the widely occurring Stone-Wales defect, can act as efficient traps for triplet excitons, characterized by significant zero-field splitting consistent with experimental data and a small singlet-triplet energy gap. Additionally, the weak electron-phonon coupling positions these defects as promising candidates for single-photon emission at telecom wavelengths (1.6 μm). These findings pave the way for enhancing the performance of carbon nanotube-based quantum light sources and optoelectronic devices.
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