Integrating metal complex units into knitted hypercrosslinked polymers for enhanced efficiency of cyclization reactions with CO

• Tác giả: Zhiyuan Chen, Yingyin Li, Ke Lin, Yinghua Lu, Rongchang Luo
• Ngôn ngữ: eng
• Ký hiệu phân loại: 551.52 Thermodynamics, atmosphere interactions with earths surface, temperatures, radiation
• Thông tin xuất bản: England : Chemical communications (Cambridge, England) , 2025
• Bộ sưu tập: NCBI
• ID: 214256

Tóm tắt

Porous hypercrosslinked polymers functionalized with aluminium porphyrins and N-heterocyclic carbene-silver complexes showed excellent catalytic properties under ambient conditions in the cycloaddition of epoxides and the carboxylative cyclization of propargylic alcohols, both with CO