Boosting Sodium Storage in Pitch-Derived Hard Carbon via MgO Catalytic Preoxidation.

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Tác giả: Yu-Guo Guo, Yu-Jie Guo, Lin-Bo Huang, Ruo-Xi Jin, Zhou-Quan Lei, Sheng-Yi Li, Haizhou Liu, Xiao-Chuan Su, Wanli Wang, Shuhao Xiao, Li Xu, Ying Xu

Ngôn ngữ: eng

Ký hiệu phân loại: 636.0885 Animal husbandry

Thông tin xuất bản: United States : ACS applied materials & interfaces , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 215172

Pitch-based hard carbon (HC) materials at low cost and high carbon yield represent a promising anode for sodium-ion batteries. However, their limited capacity poses a significant challenge to their practical use. Here, we report a universal strategy to boost sodium storage of pitch-based HC materials via catalytic oxidation with magnesium oxide to produce a high-oxygen pitch. The oxygenic groups suppress pitch softening and molecular rearrangement during carbonization, resulting in a highly disordered structure and substantially closed pores in the obtained HC materials. As a result, the optimized HC materials achieve a specific capacity of 321.7 mAh g
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