Oxidative metabolism mechanism of terpenoid compound ZQ-8 by cytochrome P450 enzyme in Helicoverpa armigera.

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Tác giả: Xiaoqiang Han, Hao Liu, Ting Ma, Chunjuan Wang, Longfei Yang, Yuting Yang, Siying Ye, Yuelan Yin, Guoqiang Zhang

Ngôn ngữ: eng

Ký hiệu phân loại: 627.12 Rivers and streams

Thông tin xuất bản: Netherlands : International journal of biological macromolecules , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 216468

In our previous research, we identified that treatment of Helicoverpa armigera with ZQ-8 led to upregulation of CYP450 genes. To clarify the metabolic pathway of ZQ-8, this study analyzed the expression of CYP450 genes and proteins in H. armigera after ZQ-8 treatment through transcriptomics and proteomics. Molecular docking, recombinant protein expression, and surface plasmon resonance techniques were employed to investigate the interactions between ZQ-8 and P450 proteins. The oxidative reduction related pathways were significantly enriched in H. armigera larvae treated with ZQ-8, with an increase in the expression of CYP6B2 and CYP6B6 genes. The CYP6B2 and CYP6B6 proteins exhibited significant expression following ZQ-8 treatment. ZQ-8 demonstrated rapid binding and stable dissociation characteristics with CYP6B6, characterized by a dissociation constant (K
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