The takeover issue, especially the setting of the takeover time budget, is a critical factor restricting the implementation and development of conditionally automated vehicles. The general fixed takeover time budget has certain limitations, as it does not take into account the driver's non-driving behaviors. Here, we propose an intelligent takeover assistance system consisting of all-round sensing gloves, a non-driving behavior identification module, and a takeover time budget determination module. All-round sensing gloves based on triboelectric sensors seamlessly detect delicate motions of hands and interactions between hands and other objects, and then transfer the electrical signals to the non-driving behavior identification module, which achieves an accuracy of 94.72% for six non-driving behaviors. Finally, combining the identification result and its corresponding minimum takeover time budget obtained through the takeover time budget determination module, our system dynamically adjusts the takeover time budget based on the driver's current non-driving behavior, significantly improving takeover performance in terms of safety and stability. Our work presents a potential value in the application and implementation of conditionally automated vehicles.