Electrochemical Radical Fluorosufonylation of Allyl Bromides.

• Tác giả: Shenlin Huang, Hui Liang, Bingcong Liu, Yanju Lu
• Ngôn ngữ: eng
• Ký hiệu phân loại: 333.822 Coal
• Thông tin xuất bản: United States : Organic letters , 2025
• Bộ sưu tập: NCBI
• ID: 219946

Tóm tắt

A radical fluorosulfonylation of allyl bromides was achieved under electroreductive conditions. This catalyst-free protocol employs mild conditions and enables straightforward access to a new and structurally diverse variety of previously inaccessible allyl sulfonyl fluorides. We have also illustrated the synthetic value of this method by performing scaled-up reactions and product derivatization.