Temperature-Enhanced Ordering in Plate-like Semicrystalline Block Copolymer Single-Crystal Suspensions Studied by Real-Time SAXS/WAXS.

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Tác giả: Enyi Chi, Tianbai He, Haiying Huang, Fajun Zhang

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: United States : Langmuir : the ACS journal of surfaces and colloids , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 236729

Self-assembly of hard platelet colloids into liquid crystalline phases is typically driven by entropy, making them less sensitive to temperature changes. However, soft interaction potentials often exist in real colloidal systems, which can lead to temperature-sensitive phase transitions. Despite significant progress in understanding phase behavior in the past 2 decades, studies on temperature-dependent phase behavior remain rare, and there is limited knowledge about how soft interactions influence phase transitions upon temperature changes. In this work, we investigated a platelet colloid system in isotropic and nematic phases using small- and wide-angle X-ray scattering techniques (SAXS/WAXS) and polarized optical microscopy (POM). The system consisted of polystyrene-
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