Dynamic Liquid Crystal Elastomers for Body Heat- and Sunlight-Driven Self-Sustaining Motion via Material-Structure Synergy.

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Tác giả: Jun-Bo Hou, Xue Jiang, Zhi-Chao Jiang, Qing Liu, Yue Liu, Wei Pu, Yao-Yu Xiao, Ying Zhang, Jing Zhao, Yue Zhao

Ngôn ngữ: eng

Ký hiệu phân loại: 338.454 Automation

Thông tin xuất bản: Germany : Angewandte Chemie (International ed. in English) , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 241541

Self-sustained actuators powered by natural, low-energy sources based on liquid crystal elastomers (LCEs) are attractive as they offer high safety, abundant energy availability, and practicality in applications. However, achieving stable self-sustaining motion with low-energy sources requires high actuation strain rates within a narrow temperature range near ambient conditions-a great challenge as LCEs with low nematic-to-isotropic transition temperatures (Tni) generally exhibit reduced actuation strain and strain rates. To address this, we synthesized a carbon nanotube-doped LCE with a low Tni and reversible Diels-Alder crosslinks, termed DALCE, and readily (re)fabricated it into specific structures (e.g., twisted-and-coiled or bimorph shapes). By leveraging material-structure synergy, we achieved both low Tni and high actuation strain rates, enabling self-rolling, self-breathing and autonomous twisting-untwisting movements powered by ambient/body temperature or natural sunlight. This low-energy, self-sustained actuator design opens new possibilities for LCE-based biomedical applications and naturally powered automatic devices.
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