A non-precious metal hydrogen catalyst in a commercial polymer electrolyte membrane electrolyser [electronic resource]

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Tác giả:

Ngôn ngữ: eng

Ký hiệu phân loại: 620.186 *Aluminum

Thông tin xuất bản: Washington, D.C. : Oak Ridge, Tenn. : United States. Dept. of Energy. Office of Science ; Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2019

Mô tả vật lý: Size: p. 1071-1074 : , digital, PDF file.

Bộ sưu tập: Metadata

ID: 255615

 We demonstrate the translation of a low-cost, non-precious metal cobalt phosphide (CoP) catalyst from 1 cm2 lab-scale experiments to a commercial-scale 86 cm2 polymer electrolyte membrane (PEM) electrolyser. A two-step bulk synthesis was adopted to produce CoP on a high-surface-area carbon support that was readily integrated into an industrial PEM electrolyser fabrication process. The performance of the CoP was compared head to head with a platinum-based PEM under the same operating conditions (400 psi, 50 �C). CoP was found to be active and stable, operating at 1.86 A cm-2 for >
 1,700 h of continuous hydrogen production while providing substantial material cost savings relative to platinum. This work illustrates a potential pathway for non-precious hydrogen evolution catalysts developed in past decades to translate to commercial applications.
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