Late transition metal m-or chemistry and D6 metal complex photoeliminations [electronic resource]

• Ngôn ngữ: eng
• Ký hiệu phân loại: 500.636 Natural sciences and mathematics
• Thông tin xuất bản: Washington, D.C. : Oak Ridge, Tenn. : United States. Dept. of Energy. Office of Science ; Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2015
• Mô tả vật lý: Size: 5 p. : , digital, PDF file.
• Bộ sưu tập: Metadata
• ID: 256494
• Chủ đề: 1. 14 solar energy; 2. 30 direct energy conversion; 3. 37 inorganic, organic, physical, and analytical chemistry

Tóm tắt

With the goal of understanding and controlling photoreductive elimination reactions from d6 transition metal complexes as part of a solar energy storage cycle we have investigated the photochemistry of Pt(IV) bromo, chloro, hydroxo, and hydroperoxo complexes. Photoreductive elimination reactions occur for all of these complexes and appear to involve initial Pt-Br, Pt-Cl, or Pt-O bond fission. In the case of Pt-OH bond fission, the subsequent chemistry can be controlled through hydrogen bonding to the hydroxo group.