Performance Assessment of Single Electrode-Supported Solid Oxide Cells Operating in the Steam Electrolysis Mode [electronic resource]

• Ngôn ngữ: eng
• Ký hiệu phân loại: 660.6 Biotechnology
• Thông tin xuất bản: Idaho Falls, Idaho : Oak Ridge, Tenn. : Idaho National Laboratory ; Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2011
• Mô tả vật lý: Size: 599 : , digital, PDF file.
• Bộ sưu tập: Metadata
• ID: 256848
• Chủ đề: 1. 08 hydrogen; 2. 21 specific nuclear reactors and associated plants; 3. 30 direct energy conversion; 4. Electrodes; 5. Electrolysis; 6. Electrolytes; 7. Et al; 8. Fuel cells; 9. Hydrogen production; 10. Impedance; 11. Oxides

Tóm tắt

An experimental study is under way to assess the performance of electrode-supported solid-oxide cells operating in the steam electrolysis mode for hydrogen production. Results presented in this paper were obtained from single cells, with an active area of 16 cm{sup 2} per cell. The electrolysis cells are electrode-supported, with yttria-stabilized zirconia (YSZ) electrolytes ({approx}10 {mu}m thick), nickel-YSZ steam/hydrogen electrodes ({approx}1400 {mu}m thick), and modified LSM or LSCF air-side electrodes ({approx}90 {mu}m thick). The purpose of the present study is to document and compare the performance and degradation rates of these cells in the fuel cell mode and in the electrolysis mode under various operating conditions. Initial performance was documented through a series of voltage-current (VI) sweeps and AC impedance spectroscopy measurements. Degradation was determined through long-term testing, first in the fuel cell mode, then in the electrolysis mode. Results generally indicate accelerated degradation rates in the electrolysis mode compared to the fuel cell mode, possibly due to electrode delamination. The paper also includes details of an improved single-cell test apparatus developed specifically for these experiments.