Pyrolysis of cyclopentanone [electronic resource] : A shock tube and laser absorption study

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Tác giả:

Ngôn ngữ: eng

Ký hiệu phân loại: 668.927 Technology of other organic products

Thông tin xuất bản: Washington, D.C. : Oak Ridge, Tenn. : United States. Dept. of Energy. Office of Energy Efficiency and Renewable Energy ; Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2018

Mô tả vật lý: Medium: ED : , digital, PDF file.

Bộ sưu tập: Metadata

ID: 263033

The chemical kinetics of cyclopentanone, an attractive fuel for spark ignition engines, was studied in a double-diaphragm, heated shock tube at pressures near 10atm over the temperature range of 1173-1416K. A fuel concentration of 0.5% was chosen to investigate the pressure, emission, and carbon monoxide time-histories during cyclopentanone pyrolysis in argon. CO mole fractions were measured behind reflected shock waves with a continuouswave distributed feedback quantum cascade laser at 2183.22cm-1, with no interference fromother intermediates. Measured values were compared to two recent chemical kinetic mechanisms.
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