Distribution of rare earth elements in fly ash derived from the combustion of Illinois Basin coals [electronic resource]

• Ngôn ngữ: eng
• Ký hiệu phân loại: 622.33 *Carbonaceous materials
• Thông tin xuất bản: Washington, D.C. : Oak Ridge, Tenn. : United States. Office of the Assistant Secretary of Energy for Fossil Energy ; Distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2020
• Mô tả vật lý: Size: Article No. 119990 : , digital, PDF file.
• Bộ sưu tập: Metadata
• ID: 267685
• Chủ đề: 1. 01 coal, lignite, and peat; 2. 42 engineering; 3. Energy & fuels; 4. Engineering; 5. Lanthanides

Tóm tắt

 This study examined rare earth element (REE) trends for Illinois Basin coal-sourced fly ashes, with the goal of understanding the elemental composition and resource potential for various fly ash fractions. Illinois Basin coals have a high volatile C through A bituminous rank with a moderate ash content (slightly>
 12% ash (dry basis)), about 3% sulfur, and, in general, lower concentrations of hazardous and other trace elements than many Central Appalachian coals. Fly ash from the combustion of Illinois Basin coals tends to have a high Fe<
 sub>
 2<
 /sub>
 O<
 sub>
 3<
 /sub>
  content owing to the amount of pyrite in the feed coals. The rare earth element (REE) concentrations in Illinois Basin coal-sourced fly ashes are less than that for fly ashes from the combustion of Central Appalachian coals. The Upper continental crust-corrected fly ashes show an H-type enrichment, a positive Eu<
 sub>
 N<
 /sub>
 /Eu<
 sub>
 N<
 sup>
 *<
 /sup>
 <
 /sub>
 , and, in some cases, a sharp Gd peak. For comparison, a suite of fly ashes from the combustion of a blend of eastern Kentucky coals had an H-type enrichment, a positive Eu<
 sub>
 N<
 /sub>
 /Eu<
 sub>
 N<
 sup>
 *<
 /sup>
 <
 /sub>
 , but only a minimal Gd peak. In contrast, fly ash from the combustion of the Fire Clay coal, a REE-rich coal, had a negative Eu<
 sub>
 N<
 /sub>
 /Eu<
 sub>
 N<
 sup>
 *<
 /sup>
 <
 /sub>
  and a sharp Gd peak. Finally, these results highlight the importance of feed coal composition on trace element contents of respective combustion fly ash fractions and also the unique REE enrichment patterns of the Illinois Basin fly ashes relative to the better studied fly ashes of eastern Kentucky and Central Appalachia.