Insights into effects of drying-wetting cycles on dissolved organic matter and Cd bioavailability in riparian sediments amended with microplastics.

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Tác giả: Wenjuan He, Jinying Hu, Jinhui Huang, Enjie Li, Si Liu, Haoliang Pang, Lixiu Shi, Chenyu Zhang, Wei Zhang

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: Netherlands : Environmental research , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 42480

Microplastics (MPs) affect the fractionation of cadmium (Cd) by altering physicochemical properties of sediment. However, differences in the effect of drying-wetting cycles on the bioavailability of heavy metals and dissolved organic matter (DOM) in sediment amended with MPs remain unclear. In this study, we investigated the influence of polystyrene (PS), polylactic acid (PLA), and tire wear particles (TWPs) at concentrations of 0.5% and 5% (w/w) on Cd fractionation and DOM properties of sediment under drying-wetting alternation conditions. The results showed that the surface of MPs displayed obvious increase in surface roughness and oxygen-containing functional groups after drying-wetting cycles. At the end of drying-wetting cycles, 0.5% and 5% MPs significantly decreased the sediment pH. And 5% PLA MPs and TWPs significantly increased the content of dissolved organic carbon (DOC). Besides, Cd bioavailability showed a slight decrease under wet conditions. However, 5% PLA MPs significantly increased F1 fraction by 7.82%-13.50%, which may be related to the release of additives. The aromaticity and humification degree of sediment-derived DOM were improved under drying-wetting alternation conditions. Further correlation analysis indicated that MPs indirectly affected Cd fractionation by influencing the sediment DOM properties. This study provides a new perspective for understanding the influence of MPs on the relationship between DOM and heavy metals in riparian sediments under typical hydrological condition.
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