Lithium-ion batteries (LIBs), characterized by high capacity, extended lifespan, and environmental friendliness, have emerged as a leading choice in energy storage technology. However, silicon (Si) as an anode material presents significant challenges due to excessive volumetric expansion during charge and discharge cycles, leading to structural damage and performance degradation. In this study, we investigated and successfully synthesized a Si/Super P: graphene composite material using a ball milling technique to examine the impact of carbon content ratios on the stability and specific capacity of the material. Experimental results indicated that the Si/30% Super P: 50% graphene composite demonstrated the highest electrochemical performance (initial specific capacity of 1500 mAh.g-1), maintaining stable specific capacity (Coulombic efficiency >
90%) after 100 cycles and capable of fast charge-discharge at high current rates (10C). The study underscores the importance of integrating conductive Super P carbon with graphene, which forms a conductive network enhancing Li+transport and reducing internal resistance during charging and discharging. The Si/C (graphene and Super P carbon) composite material, with the combination of Super P carbon and graphene, not only provides an effective solution to mitigate Si volumetric expansion but also extends the application potential of Si in commercial anode materials for LIBs, promising a breakthrough in modern battery technology.