Development of ketobenzothiazole-based peptidomimetic TMPRSS13 inhibitors with low nanomolar potency.

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Tác giả: Pierre-Luc Boudreault, William Champagne, Antoine Désilets, Ulrike Froehlich, Alice Gravel-Trudeau, Malihe Hassanzadeh, Alexandre Joushomme, Sabrina Lafrenière, Richard Leduc, Gabriel Lemieux, Matthieu Lepage, Karin List

Ngôn ngữ: eng

Ký hiệu phân loại: 612.647 Development of fetus

Thông tin xuất bản: England : Journal of enzyme inhibition and medicinal chemistry , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 472478

TMPRSS13, a member of the Type II Transmembrane Serine Proteases (TTSP) family, is involved in cancer progression and in respiratory virus cell entry. To date, no inhibitors have been specifically developed for this protease. In this study, a chemical library of 65 ketobenzothiazole-based peptidomimetic molecules was screened against a proteolytically active form of recombinant TMPRSS13 to identify novel inhibitors. Following an initial round of screening, subsequent synthesis of additional derivatives supported by molecular modelling revealed important molecular determinants involved in TMPRSS13 inhibition. One inhibitor, N-0430, achieved low nanomolar affinity towards TMPRSS13 activity in a cellular context. Using a SARS-CoV-2 pseudovirus cell entry model, we further demonstrated the ability of N-0430 to block TMPRSS13-dependent entry of the pseudovirus. The identified peptidomimetic inhibitors and the molecular insights into their potency gained from this study will aid in the development of specific TMPRSS13 inhibitors.
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