Statistical Mechanics Approach to DNA-Driven Droplet Deformation and Adhesion.

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Tác giả: Jasna Brujic, Sascha Hilgenfeldt, Nicolas Judd, Angus McMullen

Ngôn ngữ: eng

Ký hiệu phân loại: 530.13 Statistical mechanics

Thông tin xuất bản: United States : Physical review letters , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 474051

Adhesion of soft particles with mobile linkers is of importance in colloidal self-assembly, the binding of vesicles, and tissue organization in biology. Here we derive and experimentally test an equilibrium theory that captures the adhesion of DNA-coated emulsion droplets. Notably, we identify a transition from spherical to deformed droplet binding at a characteristic DNA coverage that depends on molecular properties and surface tension. Fitting the data reveals a weak effective binding strength of 3.7±0.3K_{B}T owing to entropic costs of confinement, crowding, and stretching. Our results pave the path to materials design informed by the choice of molecular-scale parameters.
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