XÁC NHẬN GIÁ TRỊ SỬ DỤNG CỦA PHƯƠNG PHÁP PHÂN TÍCH CÁC HỢP CHẤT BENZYL ALCOHOL TRONG MẪU NƯỚC KHAI THÁC DẦU BẰNG SẮC KÝ KHÍ KHỐI PHỔ=VALIDATION OF ANALYTICAL METHOD FOR BENZYL ALCOHOL COMPOUNDS IN OIL PRODUCTION WATER SAMPLES USING GAS CHROMATOGRAPHY-MASS SPECTROMETRY

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Tác giả: Thị Bích Chi Dương, Thị Thanh Trân Lê, Thị Kim Anh Nguyễn

Ngôn ngữ: vie

Ký hiệu phân loại:

Thông tin xuất bản: Tạp chí Phân tích Hóa, Lý và Sinh học, 2024

Mô tả vật lý: tr.1

Bộ sưu tập: Metadata

ID: 480680

In this study, a procedure to simultaneously analyze three benzyl alcohol compounds including 2fluorobenzyl alcohol (2-FBOH), 2,6-dichorobenzyl alcohol (2,6-DClBOH) and 3,4-difluorobenzyl alcohol (3,4-DFBOH) in produced water samples was developed for the application in a partitioning inter-well tracer test to determine residual oil saturation (Sor) in oilfield production. The sample was passed through a solid phase extraction column, then the column was dried under vacuum and flushed with 5 mL of acetonitrile. The obtained acetonotrile extract was measured on a gas chromatography-mass spectrometrer (GC-MS). The analytical method met AOAC requirements for detectability, recovery and repeatability. Depending on each benzyl alcohol compound, the limit of detection (LOD) of the method was in the range of 7 - 10 µg/L, the limit of quantification ( LOQ) ranges from 24 to 32 µg /L, recovery was achieved from 90 to 110% and the relative deviation values of (RSD) was below 9%.
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