Layered double hydroxides (LDH) have been used extensively as nanocontainers of corrosion inhibitors over the past few years. Besides the co-precipitation method, anion exchange is considered one of the effective methods for synthesizing this type of material. In this study, LDH systems intercalated by various anionssuch as CO32-, NO3-and Cl- were used to synthesize LDH carrying the organic corrosion inhibitor 2-benzothiazolythio-succinic acid (BTSA) through the anion exchange method. The influence of intercalated anions on the exchange efficiency, structure, and composition of LDH nanocontainer systems was clarified. The analytical results show that LDH-NO3 and LDH-Cl have effective anion exchange capabilities with BTSA. In contrast, LDH-CO3 did not exhibit this property due to the strong affinity of carbonate anions with the hydroxide layer. After 24 hours, the anion exchange process reached saturation, and nanocontainer products using LDH-Cl and LDH-NO3 precursors achieved 37,6 and 39,2 wt% BTSA loading capacity