A series of TiO2/graphene oxide (TMGx) nanocomposites were synthesized via the hydrothermal method. The X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) analyses confirm the reduction of graphene oxide (MGO) to reduced graphene oxide (rGO) in the presence of TiO2. Enhanced MGO loading increases the material's surface area and mitigates the aggregation of TiO2 nanotubes on the MGO surface. The X-ray Photoelectron Spectroscopy (XPS) method, complemented by UV-Vis spectra, reveals the formation of Ti-O-C bonds, which function as electron transport pathways from TiO2 to MGO, thereby reducing electron/hole recombination and extending light absorption into the visible spectrum, narrowing the bandgap (Ebg) relative to TiO2 nanotubes. The TMG5 catalyst demonstrated the highest degradation efficiency for RR195 dye among the catalysts studied. Within 20 minutes of reaction, TMG5 achieved complete removal of RR195 dye, with TOC mineralization reaching 75% after 60 minutes of catalytic ozone oxidation synergistic photocatalysis (COP). However, further increasing MGO content slightly decreased the catalytic activity of RR195 (with TOC reaching 70% after 60 minutes), attributed to the shielding effect of MGO which covers TiO2 active sites and obstructs light penetration.