Quasi-metallic bandgap tunability at low static pressures and quintuple chromism by electron transfer in a viologen-derivative iodide.

• Tác giả: Kang-Jing Li, Shi-Li Li, Zhikai Qi, Xian-Ming Zhang, Yan Zhang
• Ngôn ngữ: eng
• Thông tin xuất bản: United States : Journal of colloid and interface science , 2025
• Bộ sưu tập: NCBI
• ID: 487772

Tóm tắt

The metallized bandgap tunability at low static pressures is of vital importance to alter and optimize optical and electrical properties but it is a great challenge due to the intrinsic difficulty in reducing atomic or molecular space in crystals. The development for a material whose metallized bandgap tunability at low static pressures is accompanied by electron donor-acceptor transfer is more important because it may incorporate electron transfer related properties such as chromism. Herein, the integration of photoresponsive electron-deficient viologen ligand and electron-riched iodide ion gives rise to a charge-transfer material, [CBBPY]I