Molecular-dipole oriented universal growth of conjugated polymers into semiconducting single-crystal thin films.

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Tác giả: Zuoyuan Dong, Xinrui Guo, Ming He, Ru Huang, Lang Jiang, Xilin Lai, Dawei Liu, Shaochuan Luo, Jiamin Tian, Chunyan Zhao, Dongshan Zhou

Ngôn ngữ: eng

Ký hiệu phân loại: 344.04638 Labor, social service, education, cultural law

Thông tin xuất bản: England : Nature communications , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 49031

Precise control over crystallinity and morphology of conjugated polymers (CPs) is essential for progressing organic electronics. However, manufacturing single-crystal thin films of CPs presents substantial challenges due to their complex molecular structures, distorted chain conformations, and unbalanced crystallization kinetics. In this work, we demonstrate a universal nanoconfined molecular-dipole orientating strategy to craft high-quality single-crystal thin films for a variety of CPs, spanning from traditional thiophene- and theinothiophene-based homopolymers to diketopyrrolopyrrole- (i.e., p-type) and naphthalene-based (i.e., n-type) donor-acceptor copolymers. Central to this strategy is the synergetic manipulations of molecular dipoles, π-π stackings, and alkyl-alkyl interactions of CPs within our rationally-designed spatial-electrostatic confinement capacitor, which facilitates the rotation of conjugated backbones and the alignment of π-π stackings into microscale-sized single-crystal thin films. A minimal energetic disorder of 25 meV that below the thermal fluctuation energy k
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