Bimetallic lanthanide metal-organic framework supported ratiometric molecularly imprinted fluorescence sensor: An innovation for selective and visual detection of dimethyl phthalate.

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Tác giả: Baoqing Bai, Tao Bo, Ying Gu, Xu Jing, Huilin Liu, Yidan Wang, Yukun Yang, Ligang Yu, Jinhua Zhang, Ying Zhang

Ngôn ngữ: eng

Ký hiệu phân loại:

Thông tin xuất bản: England : Food chemistry , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 495365

Dimethyl phthalate (DMP) is a prototypical member of the phthalic acid ester class of plasticizers that may remain in food, posing a considerable risk to both food safety and human health. An innovative ratiometric fluorescence sensor (MIPs@BL-MOF) was constructed by incorporating bimetallic lanthanide terbium/europium metal-organic framework (BL-MOF) into molecularly imprinted polymers (MIPs) for the rapid selective and visual detection of DMP. In this work, BL-MOF prepared by the 'post-mixing' strategy was intelligently incorporated in the MIPs layer, giving the sensor the ability of rapid mass transfer, efficient binding, excellent anti-interference, and high selectivity. Based on the photoelectron transfer mechanism, high-affinity detection of DMP was realized by MIPs@BL-MOF with a good linear fitting (R
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