Biomass has been utilized in the carbothermal reduction method to reduce iron cations, thereby synthesizing nano zero-valent iron (nZVI). The effect of the biomass components on the regulation of the performance of prepared nZVI is not clear and the mechanism of action remains to be explored. Biomass components such as cellulose, hemicellulose, lignin, and amylum were used to prepare carbon-loaded nano zero-valent iron. It was demonstrated that increasing the cellulose content of the mixture led to higher Fe