Effect of Confined and Micellar Media on the Photo-Fries Reaction of 4-Phenoxyphenol Esters: A Valuable Key Step Toward the Preparation of Aryloxyethyl Selenocyanates.

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Tác giả: Sergio M Bonesi, Valentín Lucena, Juan B Rodriguez, Sergio H Szajnman

Ngôn ngữ: eng

Ký hiệu phân loại: 271.6 *Passionists and Redemptorists

Thông tin xuất bản: United States : The Journal of organic chemistry , 2025

Mô tả vật lý:

Bộ sưu tập: NCBI

ID: 50526

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The irradiation of a series of 4-phenoxyphenol esters in a sustainable micellar environment has been studied from both preparative and mechanistic viewpoints, and the results were compared with those obtained in cyclohexane solutions. These esters underwent the photo-Fries rearrangement reaction, and the microheterogeneous media induced a noticeable selectivity in favor of the

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