Thioether-NHC bidentate manganese complexes as efficient phosphine-free catalysts for hydrogenation at room temperature.

• Tác giả: Stéphanie Bastin, Mariia Hruzd, Sabrina L Kleynemeyer, Christophe Michon, Eric Pollet, Vincent Ritleng, Jean-Baptiste Sortais
• Ngôn ngữ: eng
• Ký hiệu phân loại: 920.71 Men
• Thông tin xuất bản: England : Chemical communications (Cambridge, England) , 2025
• Bộ sưu tập: NCBI
• ID: 54409

Tóm tắt

A series of four original phosphine-free thioether-NHC manganese complexes have been synthesised and fully characterized. These complexes have been applied as efficient catalysts for the hydrogenation of alkenes and ketones at room temperature, with low catalyst loadings (TON up to 900).