By various chromatographic methods, hederacoside C and alpha-hederin were isolated from the ethanol extract of the aerial parts of Hedera helix L.. cultivated in Da Lat, Lam Dong province. Their structures were elucidated by extensive spectroscopic methods including ID-NMR, 2D-NMR, ESI-MS, and IR. This is the first report of these compounds from H. helix, cultivated in Vietnam.